Неорганическая химия в таблицах (стр. 10 из 20)

H₂CeCl₆ 4Diox, ÍÓËÔÕ., ÑÓÂÐÉ.

F), 2.64(2 F) Ë 3.00(2 F); (SmëLu) ë ÕËÒ YF₃, ÓÑÏÃ., Í. Ú. Y 9 (ÕÓÇØÛÂÒÑÚÐÂâ ÒÓËÊÏÂ), YìF 2.3(8 F); 2.6(1 F), ÑÃÓÂÊ. ÂÐÑÏÂÎßÐÞÇ ÕÄ. Ó-ÓÞ Ô CaF₂;

(Ca,Y,Ce)F_n, n = 2ë3, "ËÕÕÓÑ×ÎáÑÓËÕ"; LnCl₃ (LaëGd) Ë LnBr₃ (LaëPr)

ÔÎÑË ËÊ ÂÐÕËÒÓËÊÏ [LnF₈] F₂(p); XeF₂

MLn₃F₁₀, M₃Ln₂F₉, Ln = DyëLu, Y

®¦´°¥½ ²¡©¥¦¦¯ªÁ Ln 1. ªÑÐÑÑÃÏÇÐÐÂâ ØÓÑÏÂÕÑÅÓÂ×Ëâ: ÔÑÓÃÙËâ Ln³⁺ РÍÂÕËÑÐËÕÂØ (Ä ÍÑÎÑÐÍÂØ) Ë

(NH₄)₃Ln₂F₉ H₂O

3s 3p 3d à.Ñ.

®ÂÅÐËÌ Mg⁰ ;: 1.2 _MCO3

4s 4p 4d MgO CaO SrO BaO RaO

¬ÂÎßÙËÌ Ca⁰ ;: 1.0 _{krist., bc., gigr.} M[O₂], ÒÇÓÇÍËÔË, ÍÓËÔÕ., ÃÙ., ÆËÂÏÂÅÐ., ÔÕÓ. ÕËÒ CaC₂,

5s 5p 5d "periklaz" "izwestx" OìO 1.49, ÔËÎßÐ. ÑÍËÔÎ.

³ÕÓÑÐÙËÌ Sr0 _;:6s 6p 6d 1.0 t.pl. 2850t.k. 3600 26142850 2430ì &20001923 ìì O₂(Sr,(Ba125<60010⁸, H±_²₎O); ÓÂÊÎ. 20MgO₂;(?) 380 (CaOÄÊÓ.² ₂₇₅₎ SrO480² BaO750²

¢ÂÓËÌ Ba⁰ ;: 0.9 £Dstr.tipaH ÿNaCl, MìO 2.11(Mg), 2.40(Ca), 2.57(Sr),598 ÿ636 ÿ590 ÿ556 ÿ544 _>600 DH ÿ623 ÿ652 ÿ640 (Õ. ÒÎ.ÿ632450)

7s 7p 7d 8H₂O; 8H₂O; 8H₂O

²ÂÆËÌ Ra0 ;: 0.9 m2.77 (=8.0(Ba);Ba), 8.9(Sr). MgO ëw g. ë mol. MO, M ì O 1.75 (Mg), 1.94 (Ba),him.inertnaposleprokaliwaniq; ÓÂÊÎ. &100

Ba_1+xO, krist.,krasn. nH₂O₂

Obrazowanie Ra priradiaktiwnomraspade: n = 0.5, 2 n=1, 2 n = 1, 2

t H₂O (ÍÓÑÏÇ MgO)

ÿ232!⁹⁰...Thaÿ! 2286.788letRa(MsThbÿ1) ÿ! 228b89ÿ;Acg ÿ! 228a;g903.64Th ÿÔÖÕ.! 224 88aRa(rqd(ThXTh)) "ÃÓÖÔËÕ"Mg(OH)₂; " Ò Ñ Ó Õ Î Â Ð -Ca(OH)₂; Sr(OH)₂; Ba(OH)₂ Ra(OH)₂

238 92U ÿ! 230 90Th ÿ! 226a;g88Ra ÿ!(rqd UëRa) ÆËÕ"

a a;g 1617 _let Õ. ÒÎ. ì ì 450 408 Ô ÓÂÊÎ. ì

²³⁵ 92Uaÿ!²²⁷ ₉₀Th_, g ^{ÿ! 223} 88Ra(^aAcX) ÿ!(rqd Ac) ±ÓÂÊÎ.² 10350ÿ¹¹ 58010ÿ⁵ 710 (?)10ÿ⁴ Ó. Ä ¯ì ₂° Ó.>Ba(OH)ì _{2 a 11.3 ÔÖÕ.}

Wydelenie ²²⁶Ra iz U-rud(&10ÿ⁵%): 1) soosavdenies BaSO₄;; nH²nO=8, 1 (Õ.ÒÎ.95,ÓÂÊÎ.125),nH²O, n=8

2) r.wkompleksonah; 3) drobnaqkristallizaciqilihromatÑÅÓÂ×Ë- 3, 2(220), 1(375)

MgO+CaO K_ÑÔÐ.2 10ÿ³ 10ÿ² 10ÿ¹ 10ÿ¹

(ËÊ "ÆÑÎÑÏËÕÂ") MO ³ÕÓ. ÕËÒ CdI₂ £ ÔÕÓ. Sr(OH)₂ MgCl₂

^MgO MìO 2.10 2.37 Í. Ú. Sr 7 (ÕÓËÅ.

ÑÆÐÑÛÂÒÑÚÐÂâ

Al [1200, ÒÓËÊÏÂ)

ÿM(AlO2)2] £ ÔÕÓ. M(OH)₂ nH₂O Í. Ú. ® 8 (ÂÐÕËÒÓËÊ- t ⁵⁾

ÏÂ), M ì O Mg(NO₃)₂, ÓÂÊÎ. >300, ÿ N₂O₄

»ÇÎÑÚÐÑÊÇÏÇÎßÐÞÇ ÏÇÕÂÎÎÞ Ra(N₃)₂ H₂O NaOH (65%) (100) neÊËÕ"), 2(₂O, n =t.pl.129)6t.pl.95,razl.100,r.wsp., "nitromagnH

Mg Ca Sr Ba Ra M(NO₃)₂, t.pl.561srazl.(Sa)ÿ!^t M(NO₂)₂ +, 570(Sr), 592(Ba, "O₂ ÿ! NO₂ + MO;nitro-

Na₂[Mg(OH)₄]; Ba₂[Mg(OH)₆]; barit"), Ra(?);

MgO 3K₂O = "K₆MgO₄", ÆÄÑÌÐÑÌ wstr. ë kubookta|dr(Sr, Ba), MìO 2.77(Sr), 2.91(Ba),

ÏÇÕ., ÃÇÎ., ÃÎÇÔÕâÜËÇ ÏâÅÍËÇ MCl₂ ÑÍËÔÇÎ, Ä ÔÕÓ. ë ÕÇÕÓÂàÆÓÞ [MgO₄] ⁴⁾ nH₂O, n = 4(Ca, t.pl.43,r.wsp.,ac.,

ÃÇÎ. ÃÇÎ. ÔÄ.-ÉÇÎÕ. ÃÇÎ. ÃÇÎ. "nitrokalxcit"; Sr, t.pl.31srazl.), 3(Ca, Õ. ÒÎ. 51), ÐÂ ÒÑÄÇÓØÐÑÔÕË ÑÍËÔÎâáÕÔâ ÄÑÊÆ., ØËÏ. ÂÍÕ. Ra4Mg 2(Ba, razl.12), 1(CaëBa, razl.&100)

ÕÑÐÚÂÌÛÂâ ÒÎÇÐÍÂ Mg(ClO ₄)₂, "angidron",^I[Mg(ClOt.pl.246,razl.382,horr.wsp.,|f.₄)₃] ¹⁵⁾ , nM(NO=4 (₂Ca,)₂, razl.240(razl.44),Sr), 217(Ba), Ra;1(Ca, Sr, Ba, ÓÂÊÎ.n>100)H₂O, r.wsp.,

MgO ÔÄÇÕËÕÔâ Ä ÕÇÏÐÑÕÇ 6H₂O, t.pl.147; M

ÆËÂÏÂÅÐ. ÒÂÓÂÏÂÅÐ. krist.,bc.,o~.gigr.M(ClO₄)₂, M = Ca, Sr((silxn.osu{iteli),hor.r.wN H₂O), Ba (razl.505), nH₂₂OO,wstr.--, n = 3, KMN₂Ba(NO₂O₂ n₂)H₄,₂segneto|lastikO;, n = 5(Sr), 4(Ba)

d 1.74 1.54 2.69 3.6 &6 ikosa|dry [BaO₁₂], BaìO 2.92 i3.03; n=1 ¹⁵⁾

Õ. ÒÎ. 651 851 1000 ¹⁰⁾ 727 969 M(ClO₃)₂, razl. 120(Sr), t.pl. 414(Ba); nH₂O, n = 6(Mg), 2(Ca),

Õ. Í. 1107 1482 1390 1860 1536 8(Sr), 1(Ba), o~.hor.r.wN₂O K₂[Ba(NO₃)₄],

E₀M2+/MÕÄ ÿ2.34 ÿ2.84 ÿ2.89 ÿ2.90 ÿ2.92 Ca(ClO)₂; 3H₂O; 1/3Ca(OH)₂ xH₂O, "belilxnaqizwestx" ÐÇÖÔÕ. ÍÑÏÒÎÇÍÔ

Ba(ClO₂)₂, razl.235

Ó. Ä ÓÂÊÃ. Í. ÓÇÂÅ. Ô ¯₂°, ÔÒ., Ó. Ä É. NH₃ (<M^I) M(BrO₃)₂ nH₂O, n = 6(Mg), 1(Ca, Sr ë horr.; Ba;), razl. >200

(ÍÓÑÏÇ HF), a-, ÍÖÃ. ÒÎ. ÖÒÂÍ. Mg(IO₃)₂, nH₂O, n = 4, 1, razl.210,hor.r.wN⁶ (Ca, "lautarit"), 10₂O;ÿ¹³ (Sr), "M(HCOwremennu`<sub>3</sub>)<sub>2</sub>, r.(" vestkostxNM = Mg, Ca<sub>2</sub>O)obuslowliwa`t

M(IO

NH₄X(?H₂+NH₃), a 5.56 6.05 10ÿ⁹ (Ba,₃)₂;,krist.,bc.,PR 10nH₂O, n = 1, 2), 10ÿ^ë14 (Ra) t ;: CO₂

R¤(?RMg¤) MìM 3.94; ; 4.30 Ba₅(IO₆)₂; M₂I₂O₉nH₂O;, M = Ca (n=8); Ba (n=3) ¹⁴⁾ MgCO₃;, "magnezit", razl.350; nH₂O, n = 2("barring-

464 2508 tonit"); 3("neskwegonit"); 5("lansfordit"),

¤ÇÍÔÂÅ. ÒÎ. ÖÒÂÍ. (ÔÕÓ. ÕËÒ Mg), ÂÕ. ë Ä ÖÊÎÂØ + H₂O ÿ! Mg₂(OH)_4ë2n(CO₃)_n mH₂O;, n=1, m=3,

ÅÇÍÔÂÅ. âÚÇÌÍË Ë Ä ÙÇÐÕÓÂØ 3-Ø ËÊ 6-ÕË ÕÓËÅ. ÒÓËÊÏ, Í. Ú. 12 MgSO₄, t.pl.1185srazl.("arkanit"), ÿ200 nH₂O, n=1 "artinit", PR = 10ÿ¹², r.w NH₄X

(ÅÇÍÔÂÅ. ÂÐÂÎÑÅ ÍÖÃÑÑÍÕÂàÆÓÂ) ("kizerit"), 2("sanderit"), 4, 5, 6("tetra-", "penta-", M₂^ICO₃, M^I = K, NH₄, Ca/2 ("dolomit") b- b- "geksagidrit "), 7, "gorxkaqsolx" ("|psomit"); Mg₅(CO₃)₄(OH)₂ 4H₂O, "gidromagnezit⁸ Pa)]; "" aragonit";

MìM=a 3.20 3.98 4.31 K₂SO₄ nH₂O, n=6 ("{enit"); 4 ("leonit") ²⁴⁾ razli~a`tsqwzaimnymraspoloveniemCaCO₃;, "kalxcit" [t.pl.1340(10 M²⁺ i CO²₃ÿ, c 5.20 6.52 ; 7.05 (NH₄)₂SO₄ 6H₂O = (NH₄)₂[Mg(H₂O)₆](SO₄)₂ ⁹; nH₂O;, n = 6, 3, 1, 0.65

605 CaSO₄;, t.pl.1450, "angidrit", ÿ!163 0.5H₂O .100 2H₂O;, razl.825SrCO₃;, ", ±² = 10stroncianitÿ ", razl.1350,t.pl.1497(r),

g-, ÍÖÃ (ÕËÒ.a-Fe) "gips", ±² = 10ÿ⁵, K = 10ÿ³ H^2O PR 10ÿ⁹

a = 4.84 5.02 5.15 M₂SO₄^{, M = H, K (} H₂O, "singenit"), NH₄, BaCO₃;, "witerit", razl.1450,t.pl.1740(r),PR 10ÿ⁹

MìM 4.19 4.44 4.53 Na("glauberit"), r.wN₂O RaCO₃;

MSO₄;, M = Sr [t.pl.1500(610⁶ Pa),razl.1580,PR 10ÿ⁷, "Magnezit" i "dolomit" izostr. "kalxcitu";

M "celestin"]; Ba[t.pl.1580srazl.,PR 10ÿ¹⁰, "barit" ("tqve- "stroncianit", "witerit" i RaCO₃ ë "aragonitu"

ÇÅÍËÇ ÔÒÎÂÄÞ Mg: NH₃ lyj{pat")]; Ra [PR 10ÿ¹²]; p. w&bsol;DTA(sm.tabl.ionow) M(CH₃COO)₂, t.pl.323srazl.(Mg), 450(Ba, wstr. ë

[Mg+Al (410%) +Zn (44%) + Mn (41.7%)] ë (Å., É.) MSO₃ nH₂O;, n = 6(Mg), 2, 4(Ca), 0(Sr, Ba) ¹⁶⁾ odno{apo~naqkwadratnaqantiprizma [BaO₈], "'àÎÇÍÕÓÑÐ"; [5ë30% Mg+Al] ë "ÏÂÅÐÂÎËÌ", ÕÄ. >Al MS₂O₃ nH₂O, n = 6 i3(Mg, Ca, hor.r.wN₂O); BaìO 2.7ë3.2 i ÕÇÕÓÂàÆÓÞ [Ba₄]); nH₂O, n = 4(Mg, 5 i1(Sr, malor.), 1 i2(Ba;) t.pl.80); 1 i2(Sa), 0.5(Sr), 3 i1(Wa),hor.r.,sl.dis. MS₂O₆ nH₂O, n = 4(Ca, Sr), 2(Ba), hor.r.wN₂O SrH(CH₃COO)₃ 2H₂O, dodeka|dr, SrìO &2.55

[M(NH₃)₆], ÍÓËÔÕ., ÊÑÎÑÕËÔÕÞÇ, Ô ÏÇÕ. ÃÎÇÔÍÑÏ, MSeOMTeO₄₄;, M = Ca(nH₂O, n =t.pl.6(Mg,&1000)hor.r.),2(Sa,r.),0(; Ba, Ra Sr;, Ba;, Ra;) MCM(HCOO)₂O₄ nH₂,₂O 2;,Hn =₂O (M = MgìSr),2(Mg), 3, 2("u|ddelitr.wN")₂Oi1("u|wel-

ÒÓÑÄÑÆÐËÍË, ÄÑÔÒÎ. РÄÑÊÆ., ÓÂÊÎ. 12(³Â), 4(Sr),ÿ ÿ⁴ (Mg), 10ÿ⁹ (Ca),

3(Ba), ÖÔÕ. >[M^I(NH₃)₆] 0(MCrOSr;, ₄PR 10nH₂O,ÿ⁵krist.,velt.,; Ba;, Ra;, PR 10n = 7(ÿMg,¹⁰) o~.hor.r.), 2(Ca, p.), 6lit10")(Ca), 1(Sr), 0(Ba);ÿ⁸ (Sr), 10ÿ⁷ (Ba), K_disPR 10 10ÿ³

[BaDipy₄], ÓÂÊÎ. ÐÂ ÄÑÊÆ. MCr₂O₇ nH₂O, n = 3(Sr), 2(Ba), krist.,krasn.,hor.r.w H₂O

O₂ (p, t) M[O₂]₂, ÐÂÆÒÇÓÇÍËÔË, M = Mg, Sr,

Ba, ÍÓËÔÕ., ÉÇÎÕÑ-ÊÇÎ., ÒÂÓÂÏÂÅÐ., ë O2 ÓÂÊÎ.+H₂Oÿÿ30(!Mg); 50(Ba);H₂O₂+O₂+M(OH)_{2 11)}

ÿ70 (ÿO₂)

M[O₃]₂, M = Sr, Ba,

ÑÊÑÐËÆÞ ^3,11)

O₃ (×ÓÇÑÐ)

Mg₂(PO₄)(OH) 3H₂O, "kowdorskit", wstr. ë sloiokt., MgìO 1.99ë2.23

M₃(PO₄)₂;, amorf.,t.pl.1357(Mg), 1670(Ca), 1727(Ba);

nH₂O (Mg, n = 22, 8"bobxerit", 4; Ca, n = 4, 5); PR 10ÿ²⁴ (Mg), 10ÿ²⁶ (Ca), 10ÿ²⁸ (Sr), 10ÿ²³ (Ba)

M(NH₄)PO₄, nH₂O, krist.,bel., n = 6(Mg), 7(Ca)